Malingaliro Oyamba ndi Magulu a Cellulose Ether
Cellulose ether ndi gulu losunthika la ma polima opangidwa kuchokera ku cellulose, polysaccharide yopezeka mwachilengedwe yomwe imapezeka m'makoma a cellulose. Ma cellulose ethers amagwiritsidwa ntchito kwambiri m'mafakitale osiyanasiyana chifukwa cha mawonekedwe awo apadera, omwe amaphatikizapo kukhuthala, kusunga madzi, kupanga mafilimu, ndi luso lokhazikika. Nawa malingaliro oyambira ndi magulu a cellulose ether:
Malingaliro Oyamba:
- Mapangidwe a Cellulose:
- Ma cellulose amapangidwa ndi mayunitsi obwerezabwereza omwe amalumikizana ndi β(1→4) glycosidic bond. Amapanga maunyolo aatali, ozungulira omwe amapereka chithandizo chomangira ku ma cell.
- Etherification:
- Ma cellulose ethers amapangidwa kudzera mu kusintha kwa mankhwala a cellulose poyambitsa magulu a ether (-OCH3, -OCH2CH2OH, -OCH2COOH, etc.) pamagulu a hydroxyl (-OH) a molekyulu ya cellulose.
- Kagwiridwe ntchito:
- Kuyamba kwa magulu a ether kumasintha mankhwala ndi thupi la cellulose, kupatsa cellulose ethers ntchito zapadera monga kusungunuka, kukhuthala, kusunga madzi, ndi kupanga mafilimu.
- Biodegradability:
- Ma cellulose ethers ndi ma polima omwe amatha kuwonongeka, kutanthauza kuti amatha kuphwanyidwa ndi tizilombo tating'onoting'ono m'chilengedwe, zomwe zimapangitsa kuti pakhale zinthu zopanda vuto.
Gulu:
Ma cellulose ether amagawidwa kutengera mtundu wamagulu a ether omwe amalowetsedwa pa molekyulu ya cellulose ndi kuchuluka kwawo m'malo. Mitundu yodziwika bwino ya ma cellulose ethers ndi awa:
- Methyl cellulose (MC):
- Methyl cellulose amapangidwa poyambitsa magulu a methyl (-OCH3) pa molekyulu ya cellulose.
- Imasungunuka m'madzi ozizira ndipo imapanga njira zowonekera, zowoneka bwino. MC imagwiritsidwa ntchito ngati thickener, stabilizer, ndi filimu kale mu ntchito zosiyanasiyana.
- Ma cellulose a Hydroxyethyl (HEC):
- Hydroxyethyl cellulose imapezeka poyambitsa magulu a hydroxyethyl (-OCH2CH2OH) pa molekyulu ya cellulose.
- Imawonetsa bwino kusungirako madzi komanso kukhuthala, kupangitsa kuti ikhale yoyenera kugwiritsidwa ntchito popaka utoto, zomatira, zodzoladzola, ndi mankhwala.
- Hydroxypropyl Methyl Cellulose (HPMC):
- Hydroxypropyl methyl cellulose ndi copolymer ya methyl cellulose ndi hydroxypropyl cellulose.
- Amapereka zinthu zoyenera monga kusungunuka kwamadzi, kuwongolera kukhuthala, komanso kupanga mafilimu. HPMC imagwiritsidwa ntchito kwambiri pomanga, mankhwala, ndi zinthu zosamalira anthu.
- Carboxymethyl cellulose (CMC):
- Carboxymethyl cellulose amapangidwa poyambitsa magulu a carboxymethyl (-OCH2COOH) pa molekyulu ya cellulose.
- Imasungunuka m'madzi ndipo imapanga ma viscous solution okhala ndi makulidwe abwino kwambiri komanso okhazikika. CMC imagwiritsidwa ntchito pazakudya, zamankhwala, ndi mafakitale.
- Ethyl Hydroxyethyl Cellulose (EHEC):
- Ethyl hydroxyethyl cellulose imapezeka poyambitsa magulu a ethyl ndi hydroxyethyl pa molekyulu ya cellulose.
- Imawonetsa kusungika kwamadzi, kukhuthala, ndi mawonekedwe a rheological poyerekeza ndi HEC. EHEC imagwiritsidwa ntchito muzomangamanga ndi zinthu zosamalira munthu.
Ma cellulose ethers ndi ma polima ofunikira omwe amagwiritsidwa ntchito mosiyanasiyana m'mafakitale osiyanasiyana. Kusintha kwawo kwamankhwala kudzera mu etherification kumapangitsa magwiridwe antchito osiyanasiyana, kuwapangitsa kukhala zowonjezera zowonjezera pamapangidwe a utoto, zomatira, zodzoladzola, mankhwala, zakudya, ndi zida zomangira. Kumvetsetsa mfundo zoyambira ndi magulu a cellulose ethers ndikofunikira pakusankha mtundu woyenera wa polima kuti mugwiritse ntchito mwapadera.
Nthawi yotumiza: Feb-10-2024